On the Measurement of Rotational Spectra of Monodeuterated Asymmetric Top Molecules in Natural Abundance Demonstrated for Monofluorobenzene
نویسنده
چکیده
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namensnennung 4.0 Lizenz. On the Measurement of Rotational Spectra of Monodeuterated Asymmetric Top Molecules in Natural Abundance Demonstrated for Monofluorobenzene
منابع مشابه
Control of rotational wave-packet dynamics in asymmetric top molecules
We combine newly developed experimental and theoretical methods to explore and control the rotations of asymmetric top molecules. In the low-temperature limit, the revival spectra of laser-driven rotational wave packets exhibit a fascinating quantum-mechanical structure, which is qualitatively different for asymmetric tops compared to symmetric or linear tops. With increasing fluence, the struc...
متن کاملThe rotational spectra, electric dipole moments and molecular structures of anisole and benzaldehyde.
The rotational spectra of anisole and of benzaldehyde were investigated in supersonic expansion at frequencies up to 41 GHz, and at room temperature in the millimetre-wave region, from 170 to 330 GHz. Accurate spectroscopic constants for the parent isotopomers in the ground vibrational state and for the first excited torsional state were determined for both molecules. The supersonic expansion s...
متن کاملThe Ultrafiltration Performance of Cellulose Acetate Asymmetric Membranes: A New Perspective on the Correlation with the Infrared Spectra
Integral asymmetric cellulose acetate (CA) membranes were casted by phase-inversion with formamide varying content - 22, 30 and 34% - as pore promoter. These membranes, CA-22, CA-30 and CA-34, were analyzed by infrared spectroscopy in attenuated total reflection mode (ATR-FTIR) to investigate the porous membrane matrix influence on the polymer/water/solute interactions and the selective ultrafi...
متن کاملMissing levels lead to additional lines: the influence of nuclear spin statistics on femtosecond degenerate four wave mixing spectroscopy of polyatomic systems.
We present the results of comprehensive experimental and theoretical studies of the effect of nuclear spin statistics on the structure of rotational recurrences in femtosecond degenerate four-wave mixing (fs DFWM) spectra of asymmetric top molecules. New recurrences of J-type with a period of 1/[4(B + C)] are identified in fs DFWM spectra of near-prolate tops SO2 [H. M. Frey, P. Beaud, T. Gerbe...
متن کاملAssignment and Analysis of Complex Rotational Spectra
Rotational spectra of even simple molecules can pose serious interpretational difficulties, especially in the high-J conditions of spectroscopy in the environmentally relevant mm-wave region. In recent years several useful techniques for dealing with such spectra in the laboratory have become apparent. These include the choice of the most suitable experimental tools, more detailed understanding...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 1999